The whole prayer

Standing

Isti'ādhah and Bismillah

Seeking refuge, then beginning with the name of Allah.

أَعُوذُ بِاللهِ مِنَ الشَّيْطَانِ الرَّجِيمِ · بِسْمِ اللهِ الرَّحْمَنِ الرَّحِيمِ

Aʿūdhu billāhi min ash-shayṭān ir-rajīm · Bismillāh ir-Raḥmān ir-Raḥīm

I take shelter with Allah from the devil, the one driven away. In the name of Allah, the Most Merciful, the Giver of mercy.

Why it is said here

The Qur'an itself instructs it: 'When you recite the Qur'an, seek refuge with Allah from the rejected devil' (16:98). Recitation is the moment your attention is most worth stealing, so you ask for cover first, then start in His name and not your own.